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Charge Transport in one Dimension:Dissipative and Non-Dissipative Space-Charge Limited Currents

机译:一维电荷输运:耗散和非耗散   空间电荷限制电流

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摘要

We consider charge transport in nanopores where the dielectric constantinside the nanopore is much greater than in the surrounding material, so thatthe flux of the electric fields due to the charges is almost entirely confinedto the nanopore. That means that we may model the electric fields due to chargedensities in the nanopore in terms of average properties across the nanopore assolutions of one dimensional Poisson equations. We develop basic equations foran M component system using equations of continuity to relate concentrations tocurrents, and flux equations relating currents to concentration gradients andconductivities. We then derive simplified scaled versions of the equations. Wedevelop exact solutions for the one component case in a variety of boundaryconditions using a Hopf-Cole transformation, Fourier series, and periodicsolutions of the Burgers equation. These are compared with a simpler model inwhich the scaled diffusivity is zero so that all charge motion is driven by theelectric field. In this non-dissipative case, recourse to an admissibilitycondition is utilised to obtain the physically relevant weak solution of aRiemann problem concerning the electric field. It is shown that theadmissibility condition is Poynting's theorem.
机译:我们考虑了在纳米孔中的电荷传输,其中纳米孔内部的介电常数比周围材料大得多,因此由于电荷引起的电场通量几乎完全限制在纳米孔中。这意味着我们可以根据一维泊松方程的整个纳米孔的平均性质,对由于纳米孔中的电荷引起的电场进行建模。我们使用连续性方程将浓度与电流相关联,将电流与浓度梯度和电导率相关联的通量方程式开发了M组分系统的基本方程式。然后,我们得出方程的简化比例版本。我们使用Hopf-Cole变换,傅里叶级数和Burgers方程的周期解为各种边界条件下的一个分量情况开发了精确解。将这些与较简单的模型进行比较,在模型中比例扩散系数为零,因此所有电荷运动都由电场驱动。在这种非耗散情况下,利用可容许性条件来获得与电场有关的黎曼问题的物理相关的弱解。证明了可容许条件是Poynting定理。

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